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Authors Krause, T. ; Habicher, W.D. ; Messerschmidt, M. ; Voit, B.
Title A novel method for the synthesis of alkoxyamine initiators for nitroxide-mediated radical polymerization using Mn(OAc)3 as electron-transfer reagent
Date 23.09.2004
Number 11989
Abstract <I> O</I> -substituted hydroxylamines which are known to initiate and promote nitroxide-mediated radical polymerization were synthesized in high yield by a novel and facile synthetic approach. Using the favorable Mn(OAc)<SUB>3</SUB> as electron transfer agent in the in situ generation of benzylic radicals and their trapping by nitroxide radicals provides a new powerful and more economic way to the desired alkoxyamine initiators for this controlled, living radical polymerization. TEMPO, TIPNO and the protected tris-hydroxy derivative of TIPNO were used to synthesize the appropriate alkoxyamines.
Publisher Designed Monomers and Polymers
Wikidata
Citation Designed Monomers and Polymers 7 (2004) 391-399
DOI https://doi.org/10.1163/1568555041475275
Tags nmrp initiators mn(oac)(3) alkoxyamines nitroxide radicals efficient synthesis

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