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Authors Ghorai, S. ; Mondal, D. ; Hait, S. ; Ghosh, A. K. ; Wießner, S. ; Das, A. ; De, D.
Title Devulcanization of waste rubber and generation of active sites for silica reinforcement
Date 18.10.2019
Number 57164
Abstract Each year, hundreds of millions of tires are produced and ultimately disposed into nature. To address this serious environmental issue, devulcanization could be one of the sustainable solutions that still remains as one of the biggest challenges across the globe. In this work, sulfur-vulcanized natural rubber (NR) is mechanochemically devulcanized utilizing a silane-based tetrasulfide as a devulcanizing agent, and subsequently, silica (SiO2)-based rubber composites are prepared. This method not only breaks the sulfur–sulfur cross-links but also produces reactive poly(isoprene) chains to interact with silica. The silica natural rubber composites are prepared by replacing 30% fresh NR by devulcanized NR with varying contents of silica. The composites exhibit excellent mechanical properties, tear strength, abrasion resistance, and dynamic mechanical properties as compared with the fresh natural rubber silica composites. The tensile strength of devulcanized rubber-based silica composites is ~20 MPa, and the maximum elongation strain is ~921%. The devulcanized composites are studied in detail by chemical, mechanical, and morphological analyses. Thus, the value added by the devulcanized rubber could attract the attention of recycling community for its sustainable applications.
Publisher ACS Omega
Wikidata
Citation ACS Omega 4 (2019) 17623-17633
DOI https://doi.org/10.1021/ACSOMEGA.9B01424
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