Authors
|
Johannsen, M. ; Schulze, U. ; Sahre, K. ; Komber, H. ; Voit, B.
|
Title
|
Synthesis of allyl-terminated polar macromonomers by metallocene-catalyzed polymerizations of 10-undecene-1-ol
|
Date
|
28.01.2012
|
Number
|
30827
|
Abstract
|
Poly(10-undecene-1-ol) macromonomers were synthesized by metallocene-catalyzed polymerization using vinyl chloride as a chain transfer agent. Using this technique, predominantly allyl terminated polymers could be obtained, which was verified by NMR spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS). By means of the mass spectra, a detailed interpretation of the nature of the head and end groups of these polymers was possible.
|
Publisher
|
ACS Macro Letters / American Chemical Society
|
Wikidata
|
|
Citation
|
ACS Macro Letters / American Chemical Society 1 (2012) 352-355
|
DOI
|
https://doi.org/10.1021/mz200185b
|
Tags
|
vinyl-chloride zirconocene catalysts graft-copolymers propene propylene polypropene polystyrene
|