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Authors
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Mende, M. ; Schwarz, D. ; Steinbach, C. ; Schwarz, S.
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Title
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Simultaneous adsorption of heavy metal ions and anions from aqueous solutions on chitosan - Investigated by spectrophotometry and SEM-EDX analysis
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Date
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05.12.2016
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Number
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51741
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Abstract
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Chitosan (flakes with a degree of deacetylation of 90%) was used as adsorbent for heavy metal ions in solution (copper, iron, nickel). The adsorption capacities were determined in dependence on the adsorption time and the initial metal salt concentration. With increasing adsorption time as well as the initial metal salt concentration the adsorption capacities increased. Highest adsorption capacity was achieved for copper(II)ions with 110 mg/L. Iron(II)- and nickel(II)ions adsorbed with an adsorption capacity of 80 mg/L.<br />The surface of chitosan flakes were investigated before and after the adsorption process by SEM and SEM-EDX, respectively. The formation of crystal-like structures was observed by SEM analysis for the investigation of copper(II)sulfate and iron(II)sulfate. It has been noticed that iron(II)ions oxidized before the adsorption on chitosan occurs. In comparison, the adsorption of nickel salt resulted in a smooth layer on the chitosan surface. SEM-EDX analysis revealed that sulfate adsorbs on the chitosan surface besides the metal cations used.
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Publisher
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Colloids and Surfaces A: Physicochemical and Engineering Aspects
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Wikidata
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Citation
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Colloids and Surfaces A: Physicochemical and Engineering Aspects 510 (2016) 275-282
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DOI
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https://doi.org/10.1016/j.colsurfa.2016.08.033
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Tags
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heavy metal ion adsorption chitosan natural polymers waste water treatment
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