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Title Synthesis of allyl-terminated polar macromonomers by metallocene-catalyzed polymerizations of 10-undecene-1-ol
Date 28.01.2012
Number 30827
Abstract Poly(10-undecene-1-ol) macromonomers were synthesized by metallocene-catalyzed polymerization using vinyl chloride as a chain transfer agent. Using this technique, predominantly allyl terminated polymers could be obtained, which was verified by NMR spectroscopy and matrix-assisted laser desorption ionization time-of-flight mass spectrometry (MALDI-TOF-MS). By means of the mass spectra, a detailed interpretation of the nature of the head and end groups of these polymers was possible.
Publisher ACS Macro Letters / American Chemical Society
Identifier
Citation ACS Macro Letters / American Chemical Society 1 (2012) 352-355
DOI https://doi.org/10.1021/mz200185b
Authors Johannsen, M. ; Schulze, U. ; Sahre, K. ; Komber, H. ; Voit, B.
Tags vinyl-chloride zirconocene catalysts graft-copolymers propene propylene polypropene polystyrene

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