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Title Grafting of polyfluorene by surface-initiated suzuki polycondensation
Date 06.11.2009
Number 21642
Abstract Graft work: The first surface-initiated and site-specific palladium-catalyzed Suzuki polycondensation that allows selective grafting and patterning of semiconducting and emissive poly[9,9-bis(2-ethylhexyl)fluorene] (1) at room temperature is developed (see scheme). The pattering is demonstrated by AFM (see image).
Publisher Angewandte Chemie - International Edition
Identifier
Citation Angewandte Chemie - International Edition 48 (2009) 2695-2698
DOI https://doi.org/10.1002/anie.200806217
Authors Beryozkina, T. ; Boyko, K. ; Khanduyeva, N. ; Senkovsky, V. ; Horecha, M. ; Oertel, U. ; Simon, F. ; Stamm, M. ; Kiriy, A.
Tags polyfluorene polymerizations surface chemistry suzuki polycondensation catalyst-transfer polycondensation chain-growth polymerization preferential oxidative addition cross-coupling reactions conjugated polymers self-organization brushes poly(3-alkylthioph

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