Authors
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Kaya, A. ; Jakisch, L. ; Komber, H. ; Pompe, G. ; Pionteck, J. ; Voit, B. ; Schulze, U.
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Title
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Synthesis of oxazoline functionalized polypropene using metallocene catalysts
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Date
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19.12.2000
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Number
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9272
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Abstract
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Using two different zirconocene/MAO catalyst systems, propene was copolymerized with the comonomers 2-(9-decene-1-yl)-1,3-oxazoline and 2-(4-(10- undecene-1-oxo)phenyl)-1,3-oxazoline, respectively. The catalysts used were rac-Et[Ind](2)ZrCl2 and rac-Me2Si[2-Me-4, 5-BenzInd](2)ZrCl2. Up to 0.53 mol-% oxazoline could be incorporated into polypropene. Oxazoline content, molecular weight, degree of isotacticity and melting behavior were dependent on the catalyst system, comonomer structure and comonomer concentration in the feed.
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Publisher
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Macromolecular Rapid Communications
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Wikidata
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Citation
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Macromolecular Rapid Communications 21 (2000) 1267-1271
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DOI
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https://doi.org/10.1002/1521-3927(20001101)21:17<1267::AID-MARC1267>3.0.CO;2-9
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Tags
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polar vinyl comonomers metallocene/methylaluminoxane catalyst copolymerization polymerization propylene ethylene olefins polyolefins complexes monomers
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