Authors Pilati, F. ; Montecchi, M. ; Fabbri, P. ; Synytska, A. ; Messori, M. ; Toselli, M. ; Grundke, K. ; Pospiech, D.
Title Design of surface properties of PET films: Effect of fluorinated block copolymers
Date 24.09.2007
Number 15109
Abstract This paper demonstrates that the addition of fluorinated block copolymers to PET solutions can be used to prepare PET films with controlled surface morphology, porosity and chemical composition, by exploiting the phenomenon known as breath figures (BF) formation during a spin-coating procedure. Surface features, such as number, depth and diameter of pores and chemical composition, can be tuned by varying the experimental conditions: relative humidity, solution composition and amount of the fluorinated block copolymer added to the PET solutions (in the range of 0.5-10 wt% with respect to PET). BF patterns are more evident at relatively high concentrations of PET (3 wt%) and content of fluorinated block copolymer (10 wt% with respect to PET) in the solution. According to the obtained results, the fluorinated block copolymer seems to play a role in different steps of the mechanism of BF formation. XPS measurements showed a surface composition much richer in fluorinated segments than expected from bulk composition. The combined surface roughness and surface segregation of fluorinated segments have only a limited effect on the macroscopic wettability of the surfaces.
Publisher Journal of Colloid and Interface Science
Wikidata 7
Citation Journal of Colloid and Interface Science 315 (2007) 210-222
Tags breath figures surface patterning poly(ethylene terephthalate) fluorinated block copolymers fluorine-rich surfaces porous surfaces self-organized honeycomb structured porous films breath figures polymer-films antireflection coatings macroporous membranes

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