Authors Fónagy, T. ; Schulze, U. ; Komber, H. ; Voigt, D. ; Pionteck, J. ; Ivan, B.
Title Well-defined poly(propylene-g-styrene) graft copolymers by combining quasiliving ATRP and metallocene catalysis: A semi-combinatorial approach
Date 16.05.2007
Number 15049
Abstract POLY 574 - Emerging Frontiers in Polyolefins <br /><br />The microstructure of poly(propylene-g-styrene) (PP-g-PS) graft copolymers obtained by metallocene catalyzed copolymerization of propylene and allyl-terminated polystyrene (PS-allyl) macromonomers prepared by quasiling ATRP can be controlled by the variation of reaction conditions. This semi-combinatorial approach has provided a library of data on the relation between the structure of PP-g-PS graft copolymers versus reaction conditions. These new findings offer the opportunity to prepare well-defined PP-g-PS graft copolymers with designed structural parameters and may provide the possibility to carry out further studies on the correlation between the microstructure and macroscopic properties of these graft copolymers.
Publisher Polymer Preprints
Citation Polymer Preprints 48 (2007) 207-208

Back to list