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Solid-state NMR

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high-resolution solid-state NMR based on MAS and multi pulse
proximity and internuclear distances from through-space dipolar coupling
refinement from quantum chemical calculations using CASTEP

Fields of work

Example: Structure of a radiation-modified PTFE

Refinement and local structure in Gibbsite from high-resolution 27Al and 1H NMR and CASTEP calculations
MAS spectrum of radiation-crosslinked PTFE



  • B. Fuchs, U. Scheler
    Branching and Cross-Linking in Radiation-Modified Poly(tetrafluoroethylene):A Solid-State NMR Investigation
    Macromolecules 33, (2000), 120-124
  • Vyalikh, D. Massiot, U. Scheler
    Structural characterisation of aluminium layered double hydroxides by 27Al solid-state NMR
    Solid State Nuclear Magnetic Resonance, 36, (2009), 19-23
  • A. Vyalikh, K. Zesewitz, U. Scheler
    Hydrogen bonds and local symmetry in the crystal structure of gibbsite
    Magnetic Resonance in Chemistry, 48, (2010), 877-881
  • U. Scheler
    Solid Polymers
    in: Solid-State NMR Spectroscopy: Principles and Applications, Melinda Duer, ed. (Blackwell Publishing 2002), 483-511
Solid-state NMR
Solid-state NMR


Polyelectrolytes and Dispersions

Fields of work

Nuclear magnetic resonance (NMR)