Authors Kaya, A. ; Jakisch, L. ; Komber, H. ; Pompe, G. ; Pionteck, J. ; Voit, B. ; Schulze, U.
Title Synthesis of oxazoline functionalized polypropene using metallocene catalysts
Date 19.12.2000
Number 9272
Abstract Using two different zirconocene/MAO catalyst systems, propene was copolymerized with the comonomers 2-(9-decene-1-yl)-1,3-oxazoline and 2-(4-(10- undecene-1-oxo)phenyl)-1,3-oxazoline, respectively. The catalysts used were rac-Et[Ind](2)ZrCl2 and rac-Me2Si[2-Me-4, 5-BenzInd](2)ZrCl2. Up to 0.53 mol-% oxazoline could be incorporated into polypropene. Oxazoline content, molecular weight, degree of isotacticity and melting behavior were dependent on the catalyst system, comonomer structure and comonomer concentration in the feed.
Publisher Macromolecular Rapid Communications
Citation Macromolecular Rapid Communications 21 (2000) 1267-1271
Tags polar vinyl comonomers metallocene/methylaluminoxane catalyst copolymerization polymerization propylene ethylene olefins polyolefins complexes monomers

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