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Authors
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Li, Y.; Zheng, T.; Du, Y.; Zhao, B.; Patel, H. P.; Boldt, R.; Auernhammer, G. K.; Fery, A.; Li, J.; Thiele, J.
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Title
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Titanium dioxide nanoparticles embedded in assembled dipeptide hydrogels for microfluidic photodegradation
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Date
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15.01.2024
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Number
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0
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Abstract
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Dipeptides can be self-assembled via non-covalent bonds towards functional nanostructures for diverse applications in nanotechnology. Here, we introduce a convenient microfluidics-guided dipeptide design as a platform for photodegradation of contaminants in water. Titanium dioxide (TiO2) nanoparticles (NPs) are chosen as photocatalysts due to their vastly studied properties. By using a well-defined microchannel architecture, the dipeptide N-fluorenylmethoxycarbonyl diphenylalanine (Fmoc-FF) and TiO2 NPs are efficiently mixed leading to a self-assembled Fmoc-FF hydrogel with embedded TiO2. Owing to shear-thinning and rapid self-healing of Fmoc-FF hydrogels, we can transfer and inject Fmoc-FF/TiO2 hydrogels into any other microdevice for specific applications, where these low-molecular-weight-gelator- (LMWG-)based Fmoc-FF hydrogels fill out the microchannel volume. Different morphologies of Fmoc-FF/TiO2 hydrogels are obtained by simple concentration screening of TiO2 NPs and Fmoc-FF. Owing to the density of the three-dimensionally twined Fmoc-FF nanofibers, solutions swelling the dipeptide hydrogel can be exchanged without leaching out TiO2 NPs. By further analysis, our hydrogel-filled flow cell can be employed for continuous-flow photodegradation in water under light irradiation. Especially, compared to the TiO2 NPs suspension, Fmoc-FF/TiO2 hydrogels with relatively low concentrations of TiO2 exhibit enhanced photodegradation capabilities due to better dispersion of nanoparticles. Such strategy provides a versatile platform for embedment of small inorganic catalysts or enzymes for (bio-)chemical conversion of solutes passing through the hydrogel network.
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Publisher
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Elsevier
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Wikidata
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Citation
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Journal of Colloid and Interface Science 654 (2024) 405-412
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DOI
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https://doi.org/10.1016/j.jcis.2023.09.191
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Tags
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