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Authors
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Zhang, H. ; Jakisch, L. ; Komber, H. ; Voit, B. ; Böhme, F.
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Title
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Synthesis of multifunctional coupling agents and their selective reactions with hydroxy and amino groups in the melt
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Date
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06.05.2013
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Number
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36142
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Abstract
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Three new coupling agents with different numbers of N-acyl lactam and 4H-3,1-benzoxazin-4-one groups were synthesized. A selective stepwise conversion of the coupling agents with 1-dodecanol and 1-dodecylamine was demonstrated by means of solvent-free model reactions in melt at 195 and 210 °C, respectively. These coupling agents are regarded as potential cores for the synthesis of novel star-like compounds and polymers with defined arms varying in type and lengths.
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Publisher
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Tetrahedron
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Wikidata
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Citation
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Tetrahedron 69 (2013) 3656-3663
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DOI
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https://doi.org/10.1016/j.tet.2013.03.024
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Tags
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coupling reactions benzoxazinone n-acyllactam chain extenders terminated polyamide-12 mechanical-properties polyesters reactivities
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