Authors Zhang, H. ; Jakisch, L. ; Komber, H. ; Voit, B. ; Böhme, F.
Title Synthesis of multifunctional coupling agents and their selective reactions with hydroxy and amino groups in the melt
Date 06.05.2013
Number 36142
Abstract Three new coupling agents with different numbers of N-acyl lactam and 4H-3,1-benzoxazin-4-one groups were synthesized. A selective stepwise conversion of the coupling agents with 1-dodecanol and 1-dodecylamine was demonstrated by means of solvent-free model reactions in melt at 195 and 210 °C, respectively. These coupling agents are regarded as potential cores for the synthesis of novel star-like compounds and polymers with defined arms varying in type and lengths.
Publisher Tetrahedron
Citation Tetrahedron 69 (2013) 3656-3663
Tags coupling reactions benzoxazinone n-acyllactam chain extenders terminated polyamide-12 mechanical-properties polyesters reactivities

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