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Authors Zhang, H. ; Jakisch, L. ; Komber, H. ; Voit, B. ; Böhme, F.
Title Synthesis of multifunctional coupling agents and their selective reactions with hydroxy and amino groups in the melt
Date 06.05.2013
Abstract Three new coupling agents with different numbers of N-acyl lactam and 4H-3,1-benzoxazin-4-one groups were synthesized. A selective stepwise conversion of the coupling agents with 1-dodecanol and 1-dodecylamine was demonstrated by means of solvent-free model reactions in melt at 195 and 210 °C, respectively. These coupling agents are regarded as potential cores for the synthesis of novel star-like compounds and polymers with defined arms varying in type and lengths.
Journal Tetrahedron 69 (2013) 3656-3663
DOI https://doi.org/10.1016/j.tet.2013.03.024

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