Authors
|
Yin, M. ; Bucsiova, L. ; Habicher, W.D. ; Voit, B.
|
Title
|
Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization of Functional Acryl- and Methacryl Derivatives
|
Date
|
27.07.2006
|
Number
|
13972
|
Abstract
|
The functional acrylamide tert-butyl N-acryloyl-â-alaninate (M2b) was successfully homo-and block copolymerized for the first time by a RAFT process using benzyl dithiobenzoate (BDTB) as a chain transfer agent and 2,2-azobis(isobutyronitrile) (AIBN) as an initiator. The resulting homo-and block copolymers have low polydispersities. Kinetic studies demonstrated that the RAFT process of functional acrylamide M2b proceeded in a controlled way at conversions below 50%. The further investigation showed that BDTB was an effective CTA for the RAFT-polymerization of functional acrylamides, acrylates; however, it was not a suitable CTA for the polymerization of functional methacrylic monomers.
|
Publisher
|
Journal of Nanostructured Polymers and Nanocomposites
|
Wikidata
|
|
Citation
|
Journal of Nanostructured Polymers and Nanocomposites 2 (2006) 11-21
|
DOI
|
http://www.jnpn.org/03,02,01,02.html
|
Tags
|
raft polymerization acryl- and methacryl derivatives amphiphilic block copolymer functional monomers kinetics
|