Authors Messerschmidt, M. ; Häußler, L. ; Voit, B. ; Krause, T. ; Habicher, W.D.
Title Synthesis of Boc Protected Block Copolymers Based on para-Hydroxystyrene via NMRP
Date 14.05.2004
Number 11925
Abstract Nitroxide mediated free radical polymerization (NMRP) was used for the preparation of orthogonally protected block copolymers based on para-hydroxystyrene. The polymers have a low polydispersity and an active chain end. By a series of polymer analogous reactions, a partly deprotected block copolymer was synthesized consisting of a block with unprotected phenolic OH groups and a further block which is protected by the thermolabile Boc group.
Publisher Macromolecular Symposia
Citation Macromolecular Symposia 210 (2004) 111-120
Tags diblock copolymers p-hydroxystyrene macroinitiators nmrp protecting groups free-radical polymerizations thin-films

Back to list