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Authors
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Stadermann, J. ; Erber, M. ; Komber, H. ; Brandt, J. ; Eichhorn, K.-J. ; Bönsch, M. ; Mertig, M. ; Voit, B.
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Title
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Photopatternable films of block copolymers prepared through double-click reaction
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Date
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09.04.2010
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Number
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22522
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Abstract
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Patterned alignment of functional organic molecules on surfaces is increasingly investigated due to numerous promising applications in micro- and nanotechnology. Chemical surface patterning attracts particular importance in such fields of biotechnology in which a controlled surface immobilization of biomolecules like enzymes or proteins is desired, e.g., for the development of biosensors. For various applications, the controlled, site-specific positioning of molecules or functional nanoparticles on surfaces is indeed a critical prerequisite. In particular, site-selective provision of functional groups is required for the reliable, site-specific attachment of functional molecules and, hence, the fabrication of regularly spaced functional arrays. Control over spatial distribution of chemical surface functionalities constitutes a major demand in diverse material applications, e.g., for the fabrication of DNA chips. Therefore, in this Communication we introduce, synthesized by a double-click approach, photopatternable block copolymers films allowing to provide site-specific amino functions and covalent attachment specifically on gold surfaces.
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Publisher
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Macromolecules
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Wikidata
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Citation
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Macromolecules 43 (2010) 3136-3140
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DOI
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https://doi.org/10.1021/ma100109t
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Tags
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photo copolymers acid protected terpolymers self-assembled monolayers functional polymers radical polymerization diblock copolymers chemistry surfaces templates nanolithography nanostructures
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