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Authors
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Dix, A.;Ptacek, S.;Poser, S.; Arnold, M.
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Title
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PP/PMMA Block Copolymers by Combination of ATRP and Metallocene Catalysis
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Date
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28.03.2006
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Number
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200
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Abstract
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PP-b-PMMA has been synthesized by a combination of metallocene catalysis and the controlled radical polymerization technique ATRP. Cp2ZrCl2/MAO and (Me4Cp)SiMe2(N-tert-Bu)TiCl2/MAO were used for the synthesis of atactic polypropylene. By a series of chemical modifications pp macroinitiators for the ATRP polymerization of MMA were synthesized. The PP-b-PMMA with polydispersities from 1.8-2.8 and an Mn ranging from 8 to 26 kg/mol was characterized by 1H-NMR,SEC and DSC.
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Publisher
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Macromolecular Symposia
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Wikidata
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Citation
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Macromolecular Symposia 236 (2006) 186-192
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DOI
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https://doi.org/10.1002/masy.200690054
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Tags
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