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Authors
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Beryozkina, T. ; Boyko, K. ; Khanduyeva, N. ; Senkovsky, V. ; Horecha, M. ; Oertel, U. ; Simon, F. ; Stamm, M. ; Kiriy, A.
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Title
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Grafting of polyfluorene by surface-initiated suzuki polycondensation
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Date
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06.11.2009
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Number
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21642
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Abstract
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Graft work: The first surface-initiated and site-specific palladium-catalyzed Suzuki polycondensation that allows selective grafting and patterning of semiconducting and emissive poly[9,9-bis(2-ethylhexyl)fluorene] (1) at room temperature is developed (see scheme). The pattering is demonstrated by AFM (see image).
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Publisher
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Angewandte Chemie - International Edition
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Wikidata
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Citation
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Angewandte Chemie - International Edition 48 (2009) 2695-2698
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DOI
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https://doi.org/10.1002/anie.200806217
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Tags
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polyfluorene polymerizations surface chemistry suzuki polycondensation catalyst-transfer polycondensation chain-growth polymerization preferential oxidative addition cross-coupling reactions conjugated polymers self-organization brushes poly(3-alkylthioph
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