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Authors
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Brantseva, T.V. ; Gorbatkina, Yu.A. ; Dutschk, V. ; Vogel, R. ; Grundke, K. ; Kerber, M.L.
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Title
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Modification of epoxy resin by polysulfone to improve the interfacial and mechanical properties in glass fibre composites. I. Study of processes during matrix/glass fibre interface formation
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Date
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31.12.2003
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Number
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10017
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Abstract
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The rheology of epoxy resin-polysulfone blends and wetting at the blend/glass fibre interface have been studied. Measurements were made in a rotary viscometer and in a modified Wilhelmy apparatus. It was shown that none of the blends investigated revealed non-Newtonian behaviour in the range of shear rates used. The viscosity of the blends increased as polysulfone content increased. Introduction of hardener resulted in a significant increase of the blends viscosity up to 2-3 orders of magnitude. Rheological tests suggested that 15 wt% polysulfone was the highest concentration useful for obtaining composites by solvent-free impregnation technique. These tests suggested that the structure of the cured epoxy-polysulfone blends depended on the modifier concentration. The structures of the blends differed for the blends containing 5 wt% polysulfone and 10-15 wt% polysulfone. All the blends (with the hardener) required at least 30 min at 180°C to achieve final values of the mechanical properties such as storage and loss moduli, loss tangent and complex viscosity. For all epoxy resin-polysulfone/glass fibre systems a complete wetting of the fibres was observed. Surface tension <I>vs.</I> polysulfone content dependency was found to be nonadditive. Surface tension measured was minimal for epoxy resin-5% polysulfone blend, while for other systems the values were close to that of epoxy resin. Modification of epoxy resin by polysulfone did not change the kinetics of the fibres wetting by the blends.
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Publisher
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Journal of Adhesion Science and Technology
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Wikidata
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Citation
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Journal of Adhesion Science and Technology 17 (2003) 2047-2063
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DOI
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https://doi.org/10.1163/156856103322584209
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Tags
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