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Authors He, G. ; Merlitz, H. ; Sommer, J.-U. ; He, G.
Title Molecular dynamics simulations of polyelectrolyte brushes under poor solvent conditions: Origins of bundle formation
Date 20.03.2014
Number 39925
Abstract Molecular dynamics simulations are applied to investigate salt-free planar polyelectrolyte brushes under poor solvent conditions. Starting above the T-point with a homogeneous brush and then gradually reducing the temperature, the polymers initially display a lateral structure formation, forming vertical bundles of chains. A further reduction of the temperature (or solvent quality) leads to a vertical collapse of the brush. By varying the size and selectivity of the counterions, we show that lateral structure formation persists and therefore demonstrate that the entropy of counterions being the dominant factor for the formation of the bundle phase. By applying an external compression force on the brush we calculate the minimal work done on the polymer phase only and prove that the entropy gain of counterions in the bundle state, as compared to the homogeneously collapsed state at the same temperature, is responsible for the lateral microphase segregation. As a consequence, the observed lateral structure formation has to be regarded universal for osmotic polymer brushes below the T-point.
Publisher Journal of Chemical Physics
Wikidata
Citation Journal of Chemical Physics 140 (2014) 104911
DOI https://doi.org/10.1063/1.4867466
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