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Authors
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Yin, M. ; Bucsiova, L. ; Habicher, W.D. ; Voit, B.
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Title
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Reversible Addition-Fragmentation Chain Transfer (RAFT) Polymerization of Functional Acryl- and Methacryl Derivatives
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Date
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27.07.2006
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Number
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13972
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Abstract
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The functional acrylamide tert-butyl N-acryloyl-â-alaninate (M2b) was successfully homo-and block copolymerized for the first time by a RAFT process using benzyl dithiobenzoate (BDTB) as a chain transfer agent and 2,2-azobis(isobutyronitrile) (AIBN) as an initiator. The resulting homo-and block copolymers have low polydispersities. Kinetic studies demonstrated that the RAFT process of functional acrylamide M2b proceeded in a controlled way at conversions below 50%. The further investigation showed that BDTB was an effective CTA for the RAFT-polymerization of functional acrylamides, acrylates; however, it was not a suitable CTA for the polymerization of functional methacrylic monomers.
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Publisher
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Journal of Nanostructured Polymers and Nanocomposites
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Wikidata
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Citation
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Journal of Nanostructured Polymers and Nanocomposites 2 (2006) 11-21
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DOI
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http://www.jnpn.org/03,02,01,02.html
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Tags
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raft polymerization acryl- and methacryl derivatives amphiphilic block copolymer functional monomers kinetics
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