Publications
| Authors | Iván, B. ; Fónagy, T. ; Erdey-Grúz, T. ; Holló-Szabó, G. ; Szesztay, M. ; Schulze, U. ; Pionteck, J. |
|---|---|
| Title |
End-Functional Polystyrenes via Quasiliving Atom Transfer Radical Polymerization and New Polymer Structures Therefrom
Advances in Controlled/Living Radical Polymerization, K. Matyjaszewski, ed. |
| Date | 11.08.2003 |
| Number | 11602 |
| Abstract | Polystyrenes with 2-chloro-2-phenylethyl chain end (PSt-Cl) prepared by quasiliving atom transfer radical polymerization (ATRP) are useful intermediates for the synthesis of a variety of well-defined macromolecular architectures. The preparation of star-shaped polystyrenes by quasiliving ATRP of divinylbenzene initiated by PSt-Cl and hyperbranched polystyrene by self-grafting of PSt-Cl mediated with TiCl, is carried out in the course of our studies. Allyl-terminated macromonomers were also prepared by reacting PSt-Cl with allyltrimethylsilane in the presence of TiCl4. This PSt-allyl was copolymerized with propylene by metallocene catalysts yielding novel poly(propylene-g-styrene) (PP-g-PSt) graft copolymers. <br /><br />Presents new developments in controlled/living radical polymerization in three areas: atom transfer radical polymerization (ATRP), nitroxide mediated polymerization (NMP), and reversible addition-fragmentation transfer (RAFT). Also includes synthesis and characterization of many new materials.<br /><br />ISBN 0-8412-3854-5 |
| Publisher | American Chemical Society |
| Wikidata | |
| Citation | American Chemical Society (2003) 331-341 |
| DOI | https://doi.org/10.1021/bk-2003-0854.ch023 |
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