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Bon, V. ; Senkovskyy, V. ; Senkovska, I. ; Kaskel, S.
Zr(IV) and Hf(IV) based metal-organic frameworks with reo-topology

Zr and Hf based MOFs with enhanced pore accessibility for large molecules and good hydrothermal stability were obtained using a bent dithienothiophene dicarboxylate and Zr4+ or Hf4+ source. A modulator (benzoic acid) facilitates formation of an eight-connecting cluster leading to a new framework which adopts reo topology.

Quelle
Chemical Communications 48, 8407-8409

DOI
http://dx.doi.org/10.1039/C2CC34246D

Erschienen am
August 2012
 
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