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Liu, W. ; Herrmann, A.-K. ; Geiger, D. ; Borchardt, L. ; Simon, F. ; Kaskel, S. ; Gaponik, N. ; Eychmüller, A.
High-performance electrocatalysis on palladium aerogels

Nanostructures as catalysts: Pd aerogels modified with a-, ß-, and ·-cyclodextrins can be obtained by the spontaneous self-assembly of in situ generated Pd nanoparticles. The Pd aerogels show excellent electrocatalytic activity for the oxidation of ethanol. The catalytic activity is believed to arise from the nonsupported nanometer-scale structure of the aerogel network and the interactions of ethanol with the cyclodextrin.

Quelle
Angewandte Chemie - International Edition 51, 5743-5747

DOI
http://dx.doi.org/10.1002/anie.201108575

Erschienen am
June 2012
 
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