Malanin, M. ; Eichhorn, K.-J. ; Lederer, A. ; Treppe, P. ; Adam, G. ; Fischer, D. ; Voigt, D.
On-line preferential solvation studies of polymers by coupled chromatographic-fourier transform infrared spectroscopic flow-cell technique
Qualitative and quantitative comparison between liquid chromatography (LC) and LC coupled with Fourier transform infrared spectroscopy (LC-FTIR) to evaluate preferential solvation phenomenon of polymers in a mixed solvent has been performed. These studies show that LC-FTIR technique leads to detailed structural information without the requirement for determination of additional parameters for quantitative analysis except calibration. Appropriate experimental conditions for preferential solvation study have been established by variation of polymer concentration, molar mass and eluent content.
Source
Journal of Chromatography / A 1216, 8939-8946
DOI
http://dx.doi.org/10.1016/j.chroma.2009.10.062
Published
November 2009
On-line preferential solvation studies of polymers by coupled chromatographic-fourier transform infrared spectroscopic flow-cell technique
Qualitative and quantitative comparison between liquid chromatography (LC) and LC coupled with Fourier transform infrared spectroscopy (LC-FTIR) to evaluate preferential solvation phenomenon of polymers in a mixed solvent has been performed. These studies show that LC-FTIR technique leads to detailed structural information without the requirement for determination of additional parameters for quantitative analysis except calibration. Appropriate experimental conditions for preferential solvation study have been established by variation of polymer concentration, molar mass and eluent content.
Source
Journal of Chromatography / A 1216, 8939-8946
DOI
http://dx.doi.org/10.1016/j.chroma.2009.10.062
Published
November 2009
