Departments > Nanostructured Materials > Fields of Work > Polymer Templates

Polymer Templates

Co-workers

  • Radim Krenek
  • Marcus Böhme
  • Dr. Bhanu Nandan
  • Dr. Tadios Tesfu Zeru
  • Dr. Xi-Kui Liu
  • Dr. Valery Luchnikov

Thin films of block-copolymers undergo phase segregation, resulting in various regular morphologies of lamelar, cylindrical, spherical, or even more complicated structured films. Dimensions of the structures can be determined by molecular dimensions of the block-copolymers and are of the order of 5-100 nm. Using different lithographical approaches these structures may be transformed to regular arrays of submicron channels, pores, or domains of electroconductive, light emitting, magnetic materials, etc.

Coordination of the particular block with low molecular weight molecules on the first step allows to fabricate the organized structures of such a combi-like block copolymer. This morphology is then frozen by cooling the systems below glass transition temperature. On the next step the low molecular weight component is removed by dissolving in a selective solvent leaving voids and channels.

The materials with regular array of nanopores fabricated in this way can be used as membranes or templates. The templates are filled with metals or electroconductive polymers yielding thin films of practical interest for nanodevices and sensors.



Current Projects

  • Optical properties of photoactive materials prepared via polymeric templates
  • Fabrication of the nanostructured thin block-copolymer films with magnetic nanorods
  • Nanotemplates based on the self-organization of films of block copolymer supramolecular assemblies
    • Co-workers:
      • Dr. Tadios Tesfu Zeru
      • Dr. Xi-Kui Liu
  • Carbon nanotemplates for electron microscopy
    • Co-workers:
      • Dr. Valery Luchnikov
      • Prof. Hannes Lichte (TU Dresden)
      • Dr. Simon (MPI)

Co-operation

Most important Publications

  1. Tokarev, I.; Kreneke, R.; Burkov, Y.; Schmeisser, D.; Sidorenko, A.; Minko, S.; Stamm, M.
    Microphase Separation in Thin Films of Poly(styrene-block-4-vinylpyridine) Copolymer - 2-(4'-Hydroxybenzeneazo)benzoic Acid Assembly mehr
    Macromolecules 38 (2005) 507-516

  2. Stamm, M.; Minko, S.; Tokarev, I.; Fahmi, A.; Usov, D.
    Nanostructures and Functionalities in Polymer Thin Films mehr
    Macromolecular Symposia 214 (2004) 73-83

  3. Tokarev, I.; Sidorenko, A.; Minko, S.; Stamm, M.
    Switching Nanotemplates mehr
    Polymeric Materials: Science and Engineering 90 (2004) 292-293

  4. Tokarev, I.; Sydorenko, A.; Minko, S.; Stamm, M.
    Novel Supramolecular Approach to Periodic Nanostructures in Thin Polymer Films mehr
    Polymeric Materials: Science and Engineering 89 (2003) 115-116

  5. Sidorenko, A.; Tokarev, I.; Minko, S.; Stamm, M.
    Ordered Reactive Nanomembranes/Nanotemplates from Thin Films of Block Copolymer Supramolecular Assembly mehr
    Journal of the American Chemical Society 125 (2003) 12211-12216

Patents

 
Polymer Templates
Polymer Templates

Departments

Nanostructured Materials

Fields of Work